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Free, publicly-accessible full text available February 1, 2027
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Denysenkov, Vasyl; Prisner, Thomas F; Neugebauer, Petr; Stoll, Stefan; Marko, Andriy (, Journal of Magnetic Resonance)
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Schubert, Mathias; Knight, Sean; Richter, Steffen; Kühne, Philipp; Stanishev, Vallery; Ruder, Alexander; Stokey, Megan; Korlacki, Rafał; Irmscher, Klaus; Neugebauer, Petr; et al (, Applied Physics Letters)We report on terahertz (THz) electron paramagnetic resonance generalized spectroscopic ellipsometry (THz-EPR-GSE). Measurements of field and frequency dependencies of magnetic response due to spin transitions associated with nitrogen defects in 4H-SiC are shown as an example. THz-EPR-GSE dispenses with the need of a cavity, permits independently scanning field and frequency parameters, and does not require field or frequency modulation. We investigate spin transitions of hexagonal ( h) and cubic ( k) coordinated nitrogen including coupling with its nuclear spin (I = 1), and we propose a model approach for the magnetic susceptibility to account for the spin transitions. From the THz-EPR-GSE measurements, we can fully determine polarization properties of the spin transitions, and we can obtain the k coordinated nitrogen g and hyperfine splitting parameters using magnetic field and frequency dependent Lorentzian oscillator line shape functions. Magnetic-field line broadening presently obscures access to h parameters. We show that measurements of THz-EPR-GSE at positive and negative fields differ fundamentally and hence provide additional information. We propose frequency-scanning THz-EPR-GSE as a versatile method to study properties of spins in solid state materials.more » « less
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